Highly soluble magnesium oxide

for the food and food supplement industry

What is magnesium Oxide?

Magne­si­um oxi­de is a che­mi­cal com­pound with the for­mu­la MgO. Magne­si­um oxi­de is inor­ga­nic, con­sists of white crys­tals, and is nor­mal­ly inso­lu­b­le in water. It has a high ele­men­tal magne­si­um con­tent of appro­xi­m­ate­ly 58–60 % and can be used in food sup­ple­ments whe­re space is limi­t­ed, such as tablets or cap­su­les. It is also often used to increase the magne­si­um con­tent in pro­ducts that can­not be achie­ved with purely orga­nic magne­si­um sources alone.

Overview:

Magne­si­um oxi­de, con­sists of a magne­si­um cati­on (Mg²⁺) and an oxy­gen anion (O²-)

Mole­cu­lar weight: 40.3 g/mol

Bulk Den­si­ty: 150–850 g/L (depen­ding on product)

For­med by cal­ci­na­ti­on of magne­si­um hydr­o­xi­de or magne­si­um carbonate

Mine­ral con­tent in %: Approx. 60 %

How is magnesium oxide produced?

Magne­si­um oxi­de is for­med by cal­ci­na­ti­on (hea­ting a che­mi­cal com­pound below its mel­ting point to cau­se par­ti­al che­mi­cal decom­po­si­ti­on) of magne­si­um hydr­o­xi­de (Mg(OH)2) or magne­si­um car­bo­na­te (MgCO3). The cal­ci­na­ti­on tem­pe­ra­tu­re has a signi­fi­cant influence on the pro­per­ties of magne­si­um oxi­de (MgO).

In which industries and for which products can magnesium oxide be used?

In medi­ci­ne, it is used as an ant­a­cid and source of magne­si­um. In the food indus­try, it is regis­tered as a food addi­ti­ve E530, ser­ves as a pH regu­la­tor and is also appro­ved for the for­ti­fi­ca­ti­on of food pro­ducts and sup­ple­ments with magnesium.

1. Crys­tal struc­tu­re and pha­se purity:

  • Low tem­pe­ra­tures: At low cal­ci­na­ti­on tem­pe­ra­tures, an amor­phous magne­si­um oxi­de is often obtained
  • Medi­um tem­pe­ra­tures: At the­se tem­pe­ra­tures, well-crystal­li­zed MgO is usual­ly pro­du­ced. The struc­tu­re beco­mes den­ser and more crystal­li­ne, which can impro­ve the mecha­ni­cal properties
  • High tem­pe­ra­tures: Very high cal­ci­na­ti­on tem­pe­ra­tures lead to a fur­ther increase in crystal­li­ni­ty. The resul­ting MgO is very sta­ble and dense

2. Particle size and surface structure:

  • Low tem­pe­ra­tures: The resul­ting MgO often has a high spe­ci­fic sur­face area. This leads to a hig­her reac­ti­vi­ty, as more sur­face area is available for che­mi­cal reactions.
  • High tem­pe­ra­tures: The spe­ci­fic sur­face area decrea­ses. This can redu­ce the reac­ti­vi­ty of the MgO.

3. Porosity:

  • Low to medi­um tem­pe­ra­tures: MgO cal­ci­ned at lower tem­pe­ra­tures tends to have a hig­her poro­si­ty, which makes it sui­ta­ble for use as a cata­lyst or adsorbent.
  • High tem­pe­ra­tures: Poro­si­ty decrea­ses as the par­tic­les beco­me den­ser and the pore struc­tu­re par­ti­al­ly clo­ses. This can increase the den­si­ty but redu­ce the spe­ci­fic sur­face area and porosity.

4. Reactivity and solubility:

  • Low tem­pe­ra­tures: Due to the hig­her spe­ci­fic sur­face area, the MgO is more reac­ti­ve and easier to dissolve.
  • High tem­pe­ra­tures: MgO cal­ci­ned at hig­her tem­pe­ra­tures has a lower reac­ti­vi­ty and solubility.

In which food supplements is magnesium oxide typically used?

Our Inno­va mar­ket rese­arch has shown that magne­si­um oxi­de is main­ly pro­ces­sed in tablets and cap­su­les (see chart below). This is becau­se magne­si­um oxi­de is ide­al for this dosa­ge form, as its high ele­men­tal magne­si­um con­tent requi­res only a small of the raw mate­ri­al com­pared to other forms of magne­si­um com­pounds. By using our high­ly solu­b­le magne­si­um oxi­de, effer­ve­s­cent tablets and pow­der can be added to the ran­ge of useful dosa­ge forms.

Why is the solubility of magnesium important for liquid applications?

Espe­ci­al­ly in liquid appli­ca­ti­ons or dis­so­lu­ti­on appli­ca­ti­ons, the con­su­mer expects a resi­due and sedi­ment-free solu­ti­on. Pro­duct deve­lo­pers the­r­e­fo­re often look for mine­ral com­pounds that meet the­se requi­re­ments. In the past, the poor solu­bi­li­ty of magne­si­um oxi­de in water posed pro­blems for the food and sup­ple­ment indus­try. We have now found a solu­ti­on to this pro­blem with our high­ly acti­ve and solu­b­le magne­si­um oxide.

What makes our magnesium oxide a highly soluble magnesium oxide?

In tests with magne­si­um oxi­des in effer­ve­s­cent pow­ders, we found that a high­ly acti­ve magne­si­um oxi­de vari­ant dis­sol­ves sedi­ment- and resi­due-free during the dis­so­lu­ti­on time of the effer­ve­s­cent pow­der. The reason for this is the citric acid added to the solu­ti­on. It cau­ses the solu­ti­on to acqui­re an aci­dic pH value and impro­ves the ioniza­ti­on (dis­so­lu­ti­on) of the magne­si­um oxi­de. This solu­bi­li­ty descri­bed in this expe­ri­ment is also trans­fera­ble to the much stron­ger sto­mach acid. The high­ly solu­b­le magne­si­um oxi­de can be dis­sol­ved (ioni­zed) by gas­tric acid, too, and thus, is bio­available. The descri­bed high­ly solu­b­le magne­si­um oxi­de can the­r­e­fo­re be used in both dry and liquid appli­ca­ti­ons. Due to the high ele­men­tal magne­si­um con­tent, only small quan­ti­ties of our high­ly acti­ve solu­b­le magne­si­um oxi­de need to be appli­ed to achie­ve the desi­red magne­si­um con­tent in the end application.

Hochauflösendes Magnesiumoxid im Vergleich zu einem normalen Magnesiumoxid in Bezug auf Löslichkeit
The solu­bi­li­ty of the high­ly solu­b­le magne­si­um oxi­de (right) com­pared to a regu­lar magne­si­um oxi­de (left) in 2% citric acid wit­hout fur­ther addi­ti­ves is cle­ar­ly recognizable.

Bioavailability of magnesium oxide

In gene­ral, regu­lar magne­si­um oxi­des have very limi­t­ed bio­avai­la­bi­li­ty due to their poor solu­bi­li­ty. By impro­ving the solu­bi­li­ty, the bio­avai­la­bi­li­ty is also increased – as seen in the exam­p­le of our high­ly solu­b­le magne­si­um oxi­de abo­ve. The bio­avai­la­bi­li­ty of magne­si­um oxi­de can also be influen­ced by the dosa­ge form. A stu­dy shows that the bio­avai­la­bi­li­ty of magne­si­um oxi­de in effer­ve­s­cent tablets is twice as high com­pared to magne­si­um oxi­de in cap­su­les. This sug­gests that the dis­so­lu­ti­on of magne­si­um oxi­de in water (ioniza­ti­on to Mg2+) is an important pre­re­qui­si­te for its absorp­ti­on. Con­se­quent­ly, the bio­avai­la­bi­li­ty of dissolved/ionized magne­si­um oxi­de is com­pa­ra­ble to that of orga­nic magne­si­um salts (e.g. magne­si­um citra­te, magne­si­um glu­co­na­te, etc.). The­se fin­dings app­ly to the high­ly acti­ve magne­si­um oxi­de from MAGNESIA. This pro­duct offers good solu­bi­li­ty in diluted orga­nic acids such as citric acid or malic acid, which are main­ly used as aci­di­fiers in food sup­ple­ments. This makes our high­ly solu­b­le magne­si­um oxi­de ide­al for effer­ve­s­cent pow­ders and tablets, which always con­tain an acid com­po­nent per se.

Highly soluble magnesium oxide – minimum order quantity and samples

Our high­ly solu­b­le magne­si­um oxi­de is available in pow­der form. Unit sizes start from 25 kg. Samples are of cour­se available to you free of char­ge. We also offer various other qua­li­ties of clas­sic magne­si­um oxi­des for use in food and nut­ri­tio­nal sup­ple­ments. Feel free to cont­act us — our sales team and our nut­ri­tio­nists will be hap­py to sup­port you.

MAGNESIA 2225020

High­ly acti­ve solu­b­le magne­si­um oxi­de, EP, USP, FCC
Ca. 57 % Mg

Down­load the specification

Whitepaper

Read our white­pa­per on high­ly acti­ve and solu­b­le magne­si­um oxide 

Down­load the whitepaper

Contact us now

Chris­ti­an Nega and the NEM team sup­ports you with tech­ni­cal know-how and finds tail­or-made solu­ti­ons for your pro­duct idea. 

Also ask for detail­ed infor­ma­ti­on about spe­ci­fi­ca­ti­onssafe­ty data sheets or mate­ri­al samples.

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